I've gone through a couple cans of the short hair fiberglass filler. It is great stuff for areas where you need high strength or moisture resistance. It goes on bare metal with a nice deep scuff with maybe 40 or 80 grit. If you want to put more on top, I highly recommend that you again scuff the surface of the hardened filler and create a "tooth" for a mechanical bond. When that filler goes down, it has some sort of shiny coating that sits on the surface and I don't think the new filler will stick to it well.
Basically, I would put down my fiberglass filler, scuff it well with a die grinder and 40 or 80 grit and get my desired shape, put down my polyester filler (bondo) to fill the deep scratches and block sand. Block sanding fiberglass filler is a huge amount of work - the stuff is just super hard. Polyester filler is a joy to block sand.
Then, if you still have scratches (which you probably will), use a glaze like the UPOL Dolphin Glaze (or any other two part polyester putty glaze) to fill the scratches and do final sanding. With that, shoot a couple coats of urethane primer, and work up from 180 to 400 grit and you are ready to seal and paint.
pat